I have a Data Verse LookUp Column which looks up Users Table in Data Verse, and is a Data Card on the form whose Data Source is the 'Employee Details' table.

The above combo box shows all the lists of users in my tenant, that I can choose from.
The 'Employee Full Name' column in Data Verse is the shown in the following:

How would we Filter the Data Card control to show all the users except the users that have already been picked. i.e. all users except 'Jane Smith'; 'Sarah Jones'; 'Jone Doe'.
Thank you for your guidance.