If you mean the "connection" in each action in the flow, that's irrelevant for a flow that's triggered from an app. When the app is shared, the flow is shared with it, effectively making the app users "run only" users of the flow. When you add "run only" users to other types of instant flows (e.g.: "For a selected item" in SharePoint), you can specify whether the flow will use the connections defined in the flow, or the connection of the run only user. When a flow runs from a Power App, you cannot designate which connection will be used; it will always be the connection of the person currently using the app, regardless of what connection you set in the flow. So, unless the users are signing into the app with the credentials of that service account (which they probably should not be doing), the flow is running as them.