Hi,
PowerAutomateDesktop doesn't have a trigger when windows boots up. So you need a work around. Here is an example:
1. Run a powershell ICE scrip that send an email. (very easy to do)
2. Save that powershell script.
3. Run this script at when windows boots up. To do this you can: "Windowskey"+"R". An app will open.
4. Write "shell:startup" and hit ok.
5. Paste your powershell script here.
- What happens now is whenever you startup your pc, a mail will be send and here comes the next step: triggering the flow because you just received an email.
6. Create and automated cloud flow which triggers when an email is received.
7. Run an attended/unattended activity within your flow.
Enjoy!