You would not put the name with encoding as its dataverse. The display name does not mean anything (at all) as it relates to accessing it.
You need to go to the Table definition and grab the logical name, in all lower case.
So go to the Table, click Advanced, grab the logical name, which is all lower case and place that there.
The Label isn't what you ever use in dataverse, except in a Canvas app as it auto maps it to the proper logical name .
its most likely something like
prefix_primaryemail, where prefix is your solutions prefix.
P.S. There are also ways to increase the max bytes so its greater than what you see in your error. Not saying you should but you can.
Cheers
If these suggestions help resolve your issue, Please consider Marking the answer as such and also maybe a like.
Thank you!
Sincerely, Michael Gernaey