Why are you using Patch() if you can just submit the form (SubmitForm()).
anyway, you can send attachments using the Form.Updates (your attachment control should be inside a form)
Patch(
UserTab,
LookUp(
UserTab,
Title = TextInput1.Text
),
{
Title: TextInput1.Text,
EmployeeID: TextInput1.Text,
EmployeeName: TextInput2.Text,
GroupName:Dropdown5.SelectedText.GroupName,
EmployeeEmail:ListBox4.Selected.Mail,
EmployeeDep: DataCardValue17.Selected,
Designation:TextInput3.Text,
CreatedBy:User().FullName,
CreatedDate:Today(),
},
<YourFormName>.Updates
);