Hi @dflauzon2 ,
Could you please share a bit more about your scenario?
Do you mean that the 'Start Time'/'End Time' field could not pull date time value from your CDS Enttiy?
Based on the issue that you mentioned, I have made a test on my side , and don't have the issue that you mentioned. The screenshot as below:

Please make sure if the 'Start Time' field and 'End Time' field of the current record you are editing is populated with proper date time value. On your side, please set the DefaultDate property of the 'Start time' DatePicker control to following:
ThisItem.'Start Time'
or
DateValue(Text(ThisItem.'Start Time', "mm/dd/yyyy"))
Set the Default property of the Hours Dropdown box to following:
Text(Hour(ThisItem.'Start Time'),"[$-en-US]00")
Set the Default property of the Minutes Dropdown box to following:
Text(Minute(ThisItem.'Start Time'),"00")
I assume that you add a Gallery control in your app to list all available records from your Entity, you could consider add a Label inside the Gallery, set the Text property to following:
ThisItem.'Start Time'
or
ThisItem.'End Time'
then check if the Label could be populated with proper date time value, if not, it means that the 'Start Time' field or 'End Time' field of the corresponding record in your CDS Entity is Blank.
If the 'Start Time' field or 'End Time' field of the corresponding record in your CDS Entity is not Blank, but the date time value still not be pulled into your canvas app, please consider remove the CDS Entity connection from your canvas app, then re-create a new connection to your Entity from your app, then try it again in your app, check if the issue is fixed.
Best regards,