1. Put your data into a collection and load to a gallery as items. E.g. ClearCollect(colPOnumbers, tblData)
2. Set TemplateFill of your Gallery so if Title column has your PONumber it will count if it exists more than once and marks it as Red : If(CountRows(Filter(colPOnumbers, Title = ThisItem.Title))>1, Red, White)
3. You can use GroupBy(colPOnumbers, "Title", "myData") on the gallery Items property to see only once the highlighted duplicate.
4. Add a Text Label into the first record of your gallery, Text property: concat(ThisItem.myData, Text(ID), ", ") to see which records have duplicated PONumber.
5. You can finally filter those records which has more than 1 row. Filter(GroupBy(colPOnumber, "Title", "myData"), CountRows(myData) > 1 )