@Anonymous ,
Another method below, assuming your People field in SharePoint is a single select field:
1. Add the Checkbox control into your Gallery
2. On the OnCheck property of the Checkbox, enter:
Collect(CollectSelection, {Email: ThisItem.'Your People Field'.Email})
3. On the UnCheck property of the Checkbox, enter:
Remove(CollectSelection, {Email:ThisItem.'Your People Field'.Email})
4. Insert another Label control outside of your Gallery. In the Text property of that Label, enter:
Concat(CollectSelection,Email & ", ")
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Imran-Ami Khan