You would have to nest it.
The Items property of a gallery or dropdown would look like:
Sort(Distinct(datasource,column to find distinct records), column for sorting, ascending/descending)
You would collect what you want and the formula above would sort it after the fact.
That said, with the April 29 update to PowerApps, your datasource may not load entirely if you use both of those functions together since they have worked in "delegation."