Jayme, I am also trying to do the same thing you are traying: read data from brazilian standard invoices xml. I am also strugling with the same problem you are.

I tried different xpath expressions, used help from online xpath editors and testers like xpather.com and nothing works! It returns an error message saying it did not return any value or saying wrong xpath syntax:
Microsoft.Flow.RPA.Desktop.Modules.SDK.ActionException: Expressão XPath inválida fornecida ---> System.Exception: A expressão deve ser avaliada para um conjunto de nós. ---> System.Exception
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em Microsoft.Flow.RPA.Desktop.Modules.XML.Actions.Utilities.GetXmlElement(XmlNodeObject xmlNodeObject, String xpathQuery)
em Microsoft.Flow.RPA.Desktop.Modules.XML.Actions.GetXmlElementValue.Execute(ActionContext context)
em Microsoft.Flow.RPA.Desktop.Robin.Engine.Execution.ActionRunner.Run(IActionStatement statement, Dictionary`2 inputArguments, Dictionary`2 outputArguments)
I looks like there is some issue with PAD and Brazilian standard xml invoices.