Hi , @OverRatedMelin
According to your description, you want to set the combobox defaultselectedItems in the Form .
I test it in my side , it works good .

And this is my button-OnSelect:
SubmitForm(Form1);
Set(DuplicateNCR,true);
Set(LastSubmit, Form1.LastSubmit );
ResetForm(Form1);
NewForm(Form1);
We need to update the DataCard-Default property:

And the Combo box property is the Parent.Default like this, and for the combo box we do not put anything in the "Default" property.

And when i select the "X" and click the button, the result is as follows:

If I misunderstand what you mean, you can describe your needs and your expected outcomes in detail so that we can better help you.
Best Regards,
Yueyun Zhang