If you just need to know if it matches one of them simply as a validation check, I would "Read from Excel" to a List (assuming the 4 are together) or if not, you could combine to a list after they are read.
Once you have them in a list, you could say If %List% does not contain %ActualRate%, throw error.
If you don't like that option, you could do something like this. It checks each one and moves to the Label down at the bottom, but if it doesn't find a match, then stops at the "stop flow" (which could also move to a different exception flow if you would like):

Here is the code for this example:
IF ActualRate = Rate1 THEN
GOTO 'Continue Flow'
END
IF ActualRate = Rate2 THEN
GOTO 'Continue Flow'
END
IF ActualRate = Rate3 THEN
GOTO 'Continue Flow'
END
IF ActualRate = Rate4 THEN
GOTO 'Continue Flow'
END
EXIT Code: 0 ErrorMessage: $'''The Actual Rate doesn\'t match the available rates'''
LABEL 'Continue Flow'
Best of luck!