As far as I know that is not possible (and to be honest I wouldn't want to do that).
You can get rid of the GUID in the apps url by setting a URL suffix under the Apps Manage Roles area - but this is not what you are asking to do.
Edit: if you have people that are using dev and you want them to no longer have access to it then implement Security Group in Azure/Office 365 and attach it to your Dataverse instance, you then can add remove from the Security Group to give/remove access.