Hi,
I have created an app and shared with external/guest users.
Web Error: The guest users can open the app but the data from SharePoint is not visible to them unless they open the SharePoint site or list once in their system.
Mobile Error: When they are opening the app in the mobile. They are getting "Error when trying to retrieve data from the network: Assignments failed: Something went wrong."
The SharePoint sub site is shared with all of them.
Once they are opening the SharePoint link in their web browser, It automatically starts working in Power Apps as well.

@WarrenBelz @timl @RezaDorrani